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Atkins & de Paula:
Physical Chemistry for the Life Sciences

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Atkins & De Paula: Physical Chemistry for the Life Sciences
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Chemical potential of a component of an ideal solution 3.26

The variation of the chemical potential of the solvent with the composition of the solution is given by

Where x is the mole fraction of the component of interest, T is the temperature (kelvin), and R is the gas constant (J K-1 mol-1).

Note that the chemical potential of the solvent is lower in the mixture than for the pure liquid (for an ideal system). This behavior is likely to be shown by a dilute solution in which the solvent is almost pure (and obeys Raoult’s Law).

To graph the change in chemical potential (J mol-1) enter the parameter (i.e., T) and hit New Plot. Up to 5 plots can be displayed at one time. The Clear button will remove all plots. To see the parameters for each plot hit the Legend on/off button. The Redraw button will refresh the graph. This is useful when the function domain (i.e., x ) has been changed. To see the value of each plot at a given point, move your cursor to the desired location then click and hold.

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