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Atkins & de Paula:
Physical Chemistry for the Life Sciences

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Atkins & De Paula: Physical Chemistry for the Life Sciences
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Change in entropy with temperature for constant heat capacity 2.4

The entropy of a sample with heat capacity that is independent of temperature, such as a monatomic perfect gas, increases logarithmically ( as ln(T) ) as the temperature is increased. The increase is proportional to the heat capacity of the sample.

The formula is

Where C is heat capacity (either Cp or CV), and temperature is changed from Ti to Tf.

To graph the change in entropy (J K-1) enter the parameter (i.e., C) and hit New Plot. Up to 5 plots can be displayed at one time. The Clear button will remove all plots. To see the parameters for each plot hit the Legend on/off button. The Redraw button will refresh the graph. This is useful when the function domain (i.e., Tf / Ti ) has been changed. To see the value of each plot at a given point, move your cursor to the desired location then click and hold.

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