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Atkins & de Paula: Elements of Physical Chemistry 5e

Introduction

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Question 1

Calculate the radius of a spherical drop of liquid mercury of mass 0.649 g. The density of mercury is 1.36 × 104 kg m-3.

Question 2

Calculate the Coulombic potential energy of an electron at a distance of 52.9 pm from the nucleus of a helium atom.

Question 3

A photoelectron has a kinetic energy of 3.588 × 10-19 J. What is its speed?

Question 4

A lump of gold of volume 127 mm3 has a mass of 2.45 mg. Calculate the density of gold.

Question 5

In a barometer, pressure is determined by measuring the height of a column of liquid. Calculate the pressure, in units of Pa, at the bottom of a 347 mm high column of paraffin oil, of density 0.798 g cm-3.

Question 6

Calculate the amount of substance in 10.1 g of glucose, C6H12O6.

Question 7

A solution is made by dissolving 13.4 g of hydrated copper nitrate, Cu(NO3)2.3H2O, in water and making up to a volume of 250 cm3. What is the concentration of nitrate ions in the solution?

Question 8

Estimate the concentration of a dilute aqueous solution of molality 0.124 kg mol-1 at standard ambient temperature and pressure.

Question 9

Calculate the mole fraction of solute molecules in a dilute aqueous solution of concentration 50.0 mmol dm-3.

Question 10

The vapour pressure above a sample of liquid water at 80°C is 355 Torr. Express this pressure in units of kPa.

 
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